Do I need to apply primer before use this coating?

Most Paint will adhere better with Primer, I would say no, it's not Something you Have to do, but if you want the paint to stick and hold at its best. I would prime the surface first.

How many of these do I need for four rims?

I got two 16" van rims coated with about 1 and a half coats out of one can of the black. It can out looking awesome. I did the other two in silver and it didn't look nearly as good. Black is where its at for spraying rims. If doing any color besides black use a deck of cards and jamb then in between rim and tire all the way around. But black sprayed on the sidewalls looks awesome.

Can I use this for a airsoft gun

You can if you want to, but this paint is for metal. So if your airsoft gun is plastic, then I'd suggest you use a paint for plastic, like Krylon Plastic paint.

Manufacturer	Rust-Oleum
Part number	7570838
Item Weight	544 g
Product Dimensions	6.67 x 6.67 x 24.13 cm; 544.31 g
Item model number	7570838
Size	15 Ounce (Pack of 1)
Color	Gloss Almond
Style	Enamel Paint
Finish	Gloss
Material	Plastic
Pattern	Paint
Shape	shape
Item Package Quantity	1
Coverage	14 sq. ft.
Special Features	Rust Resistant
Specific uses	Interior/Exterior
Included components	Spray Paint
Batteries Included?	No
Batteries Required?	No

Professional High Performance Protective Enamel

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