will it stand the heat from car coolant?

I used this on a watering system for my garden. I would not attempt to use it in a place with that kind of heat, but I am no expert.

Do these have a small hole for built up water pressure to escape?

No, but you can drill a hole at the elbow bend to use a vacuum break fitting if necessary.

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ActiveaquaHydrofarm AAEL50 Active Aqua (10 Pack), 1/2" Elbow Connector, 1/2-Inch, Black

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